Thermalization of photoexcited electrons in bismuth investigated by time-resolved THz spectroscopy and {\it ab initio} calculations

ORAL

Abstract

The charge carrier dynamics of photoexicted bismuth generates a Drude response that evolves in time. In contrast to graphite, the plasma frequency of bismuth displays an initial increase and a subsequent decay. We have performed {\it ab initio} calculations of bulk bismuth within the density functional theory, and show that the non-monotonic behaviour of the plasma frequency is due to the presence of local minima in the conduction band: most of the photoexicted electrons first accumulate in these local minima, and reach the L point only 0.6 ps after photoexcitation.

*Support from the ANR (project PNANO ACCATTONE) and from DGA are gratefully acknowledged. Computer time was granted by GENCI (project 2210).

Authors

  • Iurii Timrov

    • Laboratoire des Solides Irradi\'es - Ecole Polytechnique - CEA DSM - CNRS UMR7642 - France
    • Ecole Polytechnique, LSI
  • Tobias Kampfrath

    • Fachbereich Physik, Freie Universitat
  • Jerome Faure

    • Ecole Polytechnique, LSI
  • Nathalie Vast

    • Laboratoire des Solides Irradi\'es - Ecole Polytechnique - CEA DSM - CNRS UMR7642 - France
    • Ecole Polytechnique, LSI
  • Christian Ast

    • Max-Planck-Institut fur Festkorperforschung
  • Christian Frischkorn

    • Fritz-Haber-Institut der Max-Planck-Gesellschaft
  • Martin Wolf

    • Fachbereich Physik, Freie Universitat
  • Paola Gava

    • Ecole Polytechnique, LSI
  • Luca Perfetti

    • Ecole Polytechnique, LSI