Coherently Coupled ZnO and VO$_{2}$ Interface studied by Photoluminescence and electrical transport across a phase transition

ORAL

Abstract

In this work we report a study of a coherently coupled interface consisting of a ZnO layer grown on top of an oriented VO$_{2}$ layer on sapphire by photoluminescence and electrical transport measurements across the VO$_{2}$ metal insulator phase transition (MIT). The photoluminescence of the ZnO layer showed a broad hysteresis induced by the phase transition of VO$_{2}$ while the width of the electrical hysteresis was narrow and unaffected by the over layer. The enhanced width of the PL hysteresis was due to the formation of defects during the MIT as evidenced by a broad hysteresis in the opposite direction to that of the band edge PL in the defect luminescense. Unlike VO$_{2}$ the defects in ZnO did not fully recover across the phase transition. From the defect luminescence data, oxygen interstitials were found to be the predominant defects in ZnO mediated by the strain from the VO$_{2}$ phase transition. Such coherently coupled interfaces could be of use in characterizing the stability of a variety of interfaces and also for novel device application.

Authors

  • Amar Srivastava

    • NUSNNI-NanoCore, National University of Singapore, Singapore
    • Department of Physics, National University of Singapore, Singapore 117542
  • S. Saha

    • NUSNNI-NanoCore, National University of Singapore, Singapore
  • A. Annadi

    • NUSNNI-NanoCore, National University of Singapore, Singapore
  • Y.L. Zhao

    • NUSNNI-NanoCore, National University of Singapore, Singapore
  • K. Gopinadhan

    • NUSNNI-NanoCore, National University of Singapore, Singapore
  • X. Wang

    • NUSNNI-NanoCore, National University of Singapore, Singapore
  • N. Naomi

    • NUSNNI-NanoCore, National University of Singapore, Singapore
  • Z.Q. Liu

    • NUSNNI-NanoCore, National University of Singapore, Singapore
  • S. Dhar

    • NUSNNI-NanoCore, National University of Singapore, Singapore
  • T.S. Herng

    • Department of Mat. Sci. and Eng, National University of Singapore, Singapore
  • Bao Nina

    • Department of Mat. Sci. and Eng, National University of Singapore, Singapore
  • - Ariando

    • NUSNNI-NanoCore, National University of Singapore, Singapore
  • Jun Ding

    • Department of Mat. Sci. and Eng, National University of Singapore, Singapore
  • T. Venkatesan

    • NUSNNI-NanoCore, National University of Singapore, Singapore
    • NUSNNI-NanoCore, National University of Singapore, Singapore 117576