Quantum spin liquid in frustrated one dimensional LiCuSbO$_4$

ORAL

Abstract

A quantum magnet, LiCuSbO$_4$, with chains of edge-sharing $S\!=\!1/2$ CuO$_6$ octahedra is reported. Short-range ordering is observed while no phase transition or spin freezing occurs down to 100 mK in zero magnetic field. Specific heat indicates a distinct low-temperature high-field phase near the 12 T saturation field. Neutron scattering shows incommensurate spin correlations with $q\!=\!0.47\pm0.01~\pi/a$ and places an upper limit of 70~$\mu$eV on a potential spin gap. Exact diagonalization of easy plane $S\!=\!1/2$ chains with competing nearest neighbor ferro- and next-nearest neighbor antiferromagnetic interactions (J$_1\!=\!-75$~K, J$_2\!=\!34$~K) accounts for the $T\!>\!2$~K bulk and neutron data. Close to a quantum critical point, free from long-range order and with an achievable saturation field, LiCuSbO$_4$ is a promising candidate material to test long-standing predictions for chiral and nematic states in quantum spin chains

*This research was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award DE-FG02- 08ER46544

Authors

  • Martin Mourigal

    • Johns Hopkins University
  • Sian Dutton

    • Princeton University
    • Department of Chemistry, Princeton University
  • Manoranjan Kumar

    • Princeton University
  • Zoltan G. Zoos

    • Princeton University
  • Jiajia Wen

    • Johns Hopkins University
  • Collin L. Broholm

    • Johns Hopkins University
  • Niels H. Andersen

    • Ris\o{}-DTU
  • Qing Huang

    • NIST Center for Neutron Research
  • Mohamed Zbiri

    • Institut Laue Langevin
  • Rasmus Toft-Petersen

    • Ris\o{}-DTU
  • Robert J. Cava

    • Princeton University