Suppression of superconductivity in Fe chalcogenides by annealing: A reverse effect to pressure

ORAL

Abstract

Superconductivity in FeTe$_{1-x}$Se$_{x}$ can be controlled by annealing, in the absence of extrinsic influences. Using neutron diffraction, we show that T$_{C}$ sensitively depends on the atomic configurations of the Te and Se ions. Low temperature annealing not only homogenizes the Te and Se ion distribution as previously observed, it suppresses T$_{C}$ because of changes in the chalcogen ions' z-parameter. In particular, the height of Te from the Fe basal plane is much reduced while that for Se shows a modest increase. These trends are reverse of the effects induced by pressure.

Authors

  • Peng Tong

    • Department of Physics, University of Virginia
  • Despina Louca

    • Department of Physics, University of Virginia
  • Anna Llobet

    • Lujan Neutron Scattering Center, Los Alamos National Laboratory
  • Jiaqiang Yan

    • Department of Materials Science and Engineering, University of Tennessee
  • Ryotaro Arita

    • Department of Applied Physics, University of Tokyo, and JST TRIP