Energy Storage and Generation from Thermopower Waves

ORAL

Abstract

We have demonstrated through simulation and experiment that the nonlinear coupling between an exothermic chemical reaction in a fuel and a nanowire or nanotube with large axial heat conduction accelerates the thermal reaction wave along the nano-conduit. The thermal conduit rapidly transports energy to unreacted fuel regions, and the reaction wave induces a concomitant thermopower wave of high power density, producing electrical current in the same direction. At up to 14 W/g, this can be substantially larger than the power density offered by current micro-scale power sources (e.g. fuel cells, batteries) and even about seven times greater than that of commercial Li-ion batteries. MEMS devices and wireless sensor networks would benefit from such high power density sources to enable functions such as communications and acceleration hampered by present power sources.

Authors

  • Joel Abrahamson

    • Massachusetts Institute of Technology
  • Sayalee Mahajan

    • Massachusetts Institute of Technology
  • Wonjoon Choi

    • Massachusetts Institute of Technology
  • Nicole Schonenbach

    • Massachusetts Institute of Technology
  • Jungsik Park

    • Massachusetts Institute of Technology
  • Michael Walsh

    • Massachusetts Institute of Technology
  • Jared Forman

    • Massachusetts Institute of Technology
  • Jae-Hee Han

    • Massachusetts Institute of Technology
  • Kourosh Kalantar-zadeh

    • RMIT University
  • Michael Strano

    • Massachusetts Institute of Technology
    • MIT - Chemical Engineering
    • MIT