Temperature-dependent Raman studies of the magnetodielectric vanadates: Ni$_{3}$V$_{2}$O$_{8}$, Co$_{3}$V$_{2}$O$_{8}$, and K$_{2}$V$_{3}$O$_{8}$

ORAL

Abstract

The kagome staircase compounds, Ni$_{3}$V$_{2}$O$_{8}$ and Co$_{3}$V$_{2}$O$_{8}$, are known to exhibit dielectric anomalies at the magnetic transitions; and inhomogenously mixed-valent K$_{2}$V$_{3}$O$_{8}$ has been shown to have a strong dependence of the dielectric constant on applied magnetic field. However, while strong spin-lattice coupling is generally associated with the complex phases and phenomena in these materials, there has been little microscopic information about this coupling. In this talk, we present temperature-dependent Raman scattering studies of Ni$_{3}$V$_{2}$O$_{8}$, Co$_{3}$V$_{2}$O$_{8}$, and K$_{2}$V$_{3}$O$_{8}$ that allow us to investigate the microscopic connection between the strong spin-lattice coupling and the magnetodielectric effects in these materials.

*Work supported by the National Science Foundation under Grant NSF DMR 08-56321.

Authors

  • M. Kim

    • Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana, Illinois, 61801, USA
  • Y. Gim

    • Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana, Illinois, 61801, USA
  • S.L. Cooper

    • Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana, Illinois, 61801, USA
  • R.J. Cava

    • Department of Chemistry, Princeton University, Princeton, New Jersey 08544