Stretched-exponential relaxation and hidden power laws in a solidifying 2D liquid

ORAL

Abstract

In a 2D Lennard-Jones liquid, the number of particles keeping their memorized nearest neighbors is found to decay stretched-exponentially; the probability for a particle to keep the same 6 nearest neighbors for a time t can be fitted with a power law. Using the lists of nearest neighbors (\textit{nn}-lists) as a topological order parameter, we studied the dynamics of the structure underlying these signature features of complexity in materials. The \textit{nn}-changes randomly appear along the boundaries of better ordered blocks at a time scale of the order of particles vibration period; these boundaries, and the shapes of the blocks, perform a next time-scale random motion. Particles diffusion includes periods of slow and fast diffusion. We discuss the feed-back interactions between nn-changes, block boundaries motion, and orientation relaxation in the system.

*This work was supported by the Non-equilibrium Energy Research Center (NERC) which is an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0000989

Authors

  • Alexander Patashinski

    • Northwestern University
  • Rafal Orlik

    • Orlik-software LLC, Poland
  • Antoni Mitus

    • Polytechnic University, Wroclaw, Poland
  • Bartosz Grzybowski

    • Northwestern University
  • Mark Ratner

    • Northwestern University