Finite-Temperature Constraint-Pairing Mean Field Theory

ORAL

Abstract

Recently Tsuchimochi and Scuseria have developed a constrained-pairing mean-field theory (CPMFT), based on the Hartree-Fock-Bogoliubov theory. Application to molecular systems shows that CPMFT can accurately describe the binding energy curve in the dissociation of molecules, where electron correlation is strong. However, because CPMFT is a zero-temperature theory, it is not suitable for the description of high-temperature superconductivity and normal state of high-temperature superconductors. Here a finite-temperature generalization is formulated for the thermodynamic state of quantum many-body systems.

*This work was supported by NSF under Grant No. CHE-0807194 and the Welch Foundation under Grant No. C-0036.

Authors

  • Jianmin Tao

    • Rice University
  • Gustavo E. Scuseria

    • Rice University
    • Rice Univ.
    • Department of Chemistry, Rice University