Terahertz and Infrared Conductivity of Large-Area Graphene

ORAL

Abstract

Graphene is predicted to offer new opportunities for terahertz (THz) science and technology. Its zero-gap linear band dispersion is expected to lead to exotic nonlinear electromagnetic properties, which can be probed through frequency-dependent conductivity measurements. Here, we use THz time-domain spectroscopy and Fourier-transform infrared spectroscopy to investigate carrier dynamics in large-area graphene grown by chemical vapor deposition. We studied both nitrogen-doped and nominally-undoped graphene; the latter had accidental doping presumably through air and acid exposure. Absorption increased with the number of graphene layers and was larger in the nominally-undoped samples especially in the 0.2-2.2 THz range. For the highest-mobility samples, we observed Drude-like frequency dependence in the THz range. Further measurements in a wider spectral range are in progress to understand the differences between these samples and the interplay between intra-band and inter-band dynamics.

Authors

  • L. Ren

    • Department of Electrical and Computer Engineering, Rice University
    • Rice Univ.
  • Qi Zhang

    • Department of Electrical and Computer Engineering, Rice University
  • Takashi Arikawa

    • Department of Electrical and Computer Engineering, Rice University
  • L.G. Booshehri

    • Department of Electrical and Computer Engineering, Rice University
    • Rice Univ., LANL
  • J. Kono

    • Department of Electrical \& Computer Engineering, Rice University
    • Rice University
    • Department of Electrical and Computer Engineering, Rice University
    • Department of Electrical Engineering, Rice University, Houston, Texas 77005
    • ECE Dept., Rice University
    • Dept. of Electrical and Computer Engineering, Rice University
    • Rice Univ.
  • Z. Jin

    • Department of Chemistry, Rice University
    • Rice Univ.
  • Zhengzong Sun

    • Department of Chemistry, Rice University
  • Z. Yan

    • Department of Chemistry, Rice University
    • Rice Univ.
  • J.M. Tour

    • Department of Chemistry, Rice University
    • Rice University
    • Rice Univ.