High Pressure Studies of UO$_{3}$
ORAL
Abstract
It has been reported that upon compression t ambient temperature $\delta $-UO3 becomes amorphous at 2.2 GPa. (Journal of Alloys and Compounds 315 p59--61). We studied the properties of $\gamma $-UO3 in diamond anvil cell up to 75 GPa. Powder diffraction experiments performed at HPCAT/Advanced Photon Source show the crystalline uranium trioxide transforms to an amorphous solid between 12 and 14 GPa and remains amorphous up to 75 GPa. The transition has been confirmed by Raman spectroscopy as well. In this paper we'll present our findings on the amorphous transition together with the equation of state of both the crystalline phase and the amorphous phase.
*This work performed under the auspices of the US DOE by LLNL under Contract DE-AC52-07NA27344 HPCAT is supported by CIW, CDAC, UNLV and LLNL through funding from DOE-NNSA, DOE-BES and NSF. APS is supported by DOE-BES, under Contract No. DE-AC02-06CH11357.
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