Metal-Insulator Transition in Ce$_{1-x}$Gd$_{x}$Fe$_{4}$P$_{12}$ (x $\sim $0.1) observed by ESR.

ORAL

Abstract

Measurements by Electron Spin Resonance (ESR) of Gd$^{3+}$ impurities doped into single crystals of CeFe$_{4}$P$_{12}$ show the evolution from fully resolved ESR spectra with Lorentzian (insulator) shape lines into a single broad ESR line with a Dysonian (metallic) shape as a function of temperature. The fine and hyperfine structure splitting of Gd$^{3+}$ is clearly observed at low temperature in the fully resolved ESR spectra. From the spectra we determined the crystal field and hyperfine structure parameters. With increasing T the ESR lines broaden and finally collapse into a single Dysonian line at about 180 K. As T increases further the linewidth becomes broader at a rate of $\sim $ 1.1 Oe/K. We discuss the origin of the ``Metal to Insulator'' transition observed.

Authors

  • M. Tovar

    • Universidad Nacional de Cuyo, Mendoza, Argentina
  • F.A. Garcia

    • UNICAMP, Campinas, Brazil
  • P.G. Pagliuso

    • UNICAMP, Campinas, Brazil
  • C. Rettori

    • UNICAMP, Campinas, Brazil
  • P.A. Venegas

    • Univ. Estadual Paulista, Brazil
  • D.J. Garcia

    • Cento Atomico Bariloche, Argentina
  • P. Schlottmann

    • Florida State University
  • M.G. Passeggi

    • INTEC, Conicet Santa Fe, Argentina
  • M.S. Torikachvili

    • San Diego State University
  • S.B. Oseroff

    • San Diego State University and Univ. Nacional de Cuyo, Argentina