Growth and Atomistic Mechanisms of Snowflake-like ZnO Islands on curved substrates

ORAL

Abstract

Various snowflake-like patterns are obtained during heretoepitaxial growth of ZnO on Zn-dominant spheres via chemical vapor deposition (CVD). Highly regular and symmetric dendritic patterns of varying compactness can be obtained at different cooling rates. Furthermore, a reduction in the relative concentration of oxygen supply leads to smooth compact islands with sharp or flat tops. The underlying atomistic formation mechanisms of these patterns are investigated using kinetic Monte Carlo simulations. We reproduce the dendritic patterns in the simulations and also propose a plausible mechanism for the growth of the compact patterns with different tops.

*Supported by NNSF, 863 and 973 programs of China, DMSE/USDOE, and USNSF

Authors

  • Guo Li

    • Institute of Physics, Chinese Academy of Sciences; U of Tennessee-Knoxville
  • Chen Li

    • Institute of Physics, Chinese Academy of Sciences
  • Chengmin Shen

    • Institute of Physics, Chinese Academy of Sciences
  • Chao Hui

    • Institute of Physics, Chinese Academy of Sciences
  • Jifa Tian

    • Institute of Physics, Chinese Academy of Sciences
  • Shixuan Du

    • Institute of Physics, Chinese Academy of Sciences
  • Hong-Jun Gao

    • Institute of Physics, Chinese Academy of Sciences
  • Zhenyu Zhang

    • Oak Ridge National Laboratory, U of Tennessee-Knoxville
    • Oak Ridge National Laboratory
    • Oak Ridge National Laboratory \& The Univeristy of Tennessee
    • Oak Ridge National Laboratory \& University of Tennessee
    • Oak Ridge National Laboratory, University of Tennessee-Knoxville
    • Oak Ridge National Laboratory and University of Tennessee
    • The Univ. Tennessee;Oak Ridge National Lab