Infrared-active excitations related to the $R^{3+}$ ligand-field splitting in $R$Mn$_{2}$O$_{5 }(R$=Ho, Dy, Tb)

ORAL

Abstract

Optical transitions between ligand-field split states of $R^{3+}$ ions in $R$Mn$_{2}$O$_{5}$ multiferroic single crystals have been studied at the phase transitions in the external magnetic field up to 13 T and uniaxial pressure up to 5 kbar. Spectra of the ligand field excitations change significantly in external magnetic field and correlate with the reversal of electric polarization induced by magnetic field. The oscillator strength and selection rules for ligand field excitations change with external uniaxial pressure. We discuss the connection between the ligand field on $R^{3+}$ with the magnetism and dielectric properties of this compounds.

*Work is supported by NSF-DMR-0546985, DE-FG02-07ER46382, and DE-AC02-98CH10886.

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Authors

  • Andrei Sirenko

    • New Jersey Institute of Technology
    • Physics Department, New Jersey Institute of Technology (NJIT), Newark, NJ 07102

  • S. M. O'Malley

    • New Jersey Institute of Technology

  • T. D. Kang

  • K. H. Kahn

    • Deptartment of Physics, NJIT, Newark, NJ

  • G.L. Carr

    • Brookhaven National Laboratory
    • NSLS, Brookhaven National Laboratory
    • NSLS, Brookhaven National Laboratory, Upton, NY
    • NSLS, Brookhaven National Lab

  • L. Mihaly

    • Department of Physics and Astronomy, Stony Brook University, NY

  • S. Park

    • Rutgers Center for Emergent Materials and Dept. of Physics \& Astronomy, Rutgers University

  • Sang-Wook Cheong

    • Rutgers University
    • Department of Physics, Rutgers University
    • Rutgers Center for Emergent Materials and Department of Physics and Astronomy, Rutgers University, Piscataway, NJ