Observation of graphene bubbles and effective mass transport under graphene films

ORAL

Abstract

Mechanically exfoliated graphene mounted on a SiO$_{2}$/Si substrate was subjected to HF/H$_{2}$O etching or irradiation by energetic protons. In both cases gas was released from the SiO$_{2}$ and accumulated at the graphene/SiO$_{2}$ interface resulting in the formation of ``bubbles'' in the graphene sheet. Formation of these ``bubbles'' demonstrates the robust nature of single layer graphene membranes, which are capable of containing mesoscopic volumes of gas. In addition, effective mass transport at the graphene/SiO$_{2}$ interface has been observed.

Authors

  • Daniil Stolyarov

    • Brookhaven National Lab
  • Elena Stolyarova

    • Columbia University
  • Kirill Bolotin

    • Columbia University
  • Li Liu

    • Columbia University
  • Sunmin Ryu

    • Columbia University
  • Kwang Rim

    • Columbia University
  • Mark Hybertsen

    • Brookhaven National Laboratory
    • Center for Functional Nanomaterials, Brookhaven National Laboratory
    • Brookhaven National Lab
  • Igor Pavlishin

    • Brookhaven National Lab
  • Martin Klima

    • Columbia University
  • Igor Pogorelsky

    • Brookhaven National Lab
  • Karl Kusche

    • Brookhaven National Lab
  • James Hone

    • Department of Mechanical Engineering, Columbia University
    • Columbia University
  • Philip Kim

    • Columbia University
    • Physics, Columbia University
    • Depts. of Physics and Applied Physics, Columbia University
    • Physics Department, Columbia University
    • Associate Professor, Physics Department, Columbia University
  • Horst Stormer

    • Columbia University
  • Vitaly Yakimenko

    • Brookhaven National Lab
  • George Flynn

    • Columbia University
    • Columbia University Nanocenter