Optical properties of LuFe$_2$O$_4$

ORAL

Abstract

We measured the optical properties of single crystalline LuFe$_2$O$_4$ as a function of temperature and compared the results with recent electronic structure calculations. The 300 K optical gap is found to be ${\sim}$ 0.4 eV. The optical conductivity is very sensitive to temperature and shows a sharp transition at around 170 K structural transition. The Fe$^{2+}$ to Fe$^{3+}$ charge transfer transition (at approximately 1.5 eV) sharpens dramatically at low temperature, a trend that may be connected with the complex charge order of the material. Preliminary high energy magneto-dielectric data will be discussed.

*This work is supported by the U.S. Department of Energy.

Authors

  • Xiaoshan Xu

    • Univeristy of Tennessee, Knoxville
  • T. V. Brinzari

    • Univeristy of Tennessee, Knoxville
    • University of Tennessee
  • Janice Musfeldt

    • University of Tennessee
    • Univeristy of Tennessee, Knoxville
  • M. Angst

    • Materials Science and Technology Division, ORNL, Oak Ridge, TN 37831
    • Oak Ridge National Laboratory
    • Oak Ridge National Laboratory, Oak Ridge TN 37831
  • David Mandrus

    • Materials Science and Technology Division, ORNL, Oak Ridge, TN 37831
    • Oak Ridge National Laboratory, Oak Ridge, TN 37831
    • Oak Ridge National Laboratory
    • Oak Ridge National Laboratory, Oak Ridge TN 37831
    • Oak Ridge Natl Lab