High-pressure x-ray diffraction study of Pb(Mg$_{1/3}$Nb$_{2/3})$O$_{3}$-32{\%}PbTiO$_{3}$.

ORAL

Abstract

Motivated to determine and understand PMN-32{\%}PT's behavior under pressure, we employed the angular dispersive x-ray diffraction methods (Advanced Photon Source, Argonne National Laboratory) to investigate PMN-32{\%}PT in a diamond anvil cell up to 15 GPa. The x-ray diffraction results show changes in Bragg peaks at 4 GPa which indicate that PMN-32{\%}PT undergoes a ferroelectric rhombohedral to a paraelectric cubic phase transition. In addition, we investigated the pressure dependence of domain structure of PMN-32{\%}PT up to 10 GPa; rhombohedral domains decrease with pressure and disappear above 4 GPa. These results are qualitatively consistent with earlier Raman study of B. Chaabane, {\{}Phys. Rev. B 70, 134114, 2004{\}}. We suggest a phase diagram for PMN-PT system which is slightly different from the one predicted by B. Chaabane et al.

*This work is supported by the ONR under the contract number N000140210506 and the Carnegie/Department of Energy Alliance Center (CDAC) (DF-FC03N00144).

Authors

  • Muhtar Ahart

    • Geophysical Laboratory
    • Carnegie Institution of Washington
  • Ronald E. Cohen

    • Carnegie Institution of Washington
  • Russell Hemley

    • Carnegie Institution for Science
    • Carnegie Institution of Washington