Excitonic Effects in the Optical Spectra of Graphene Nanoribbons

ORAL

Abstract

We present a first-principles calculation of the optical properties of graphene nanoribbons (GNRs) with many-electron effects included, employing the GW-BSE approach. The reduced dimensionality of GNRs gives rise to an enhanced electron-hole binding energy for both bright and dark exciton states and changes the optical spectra significantly. The characteristics of the excitons of different types of GNRs are compared and discussed. The enhanced excitonic effects found here are expected to be of importance in considering possible applications (such as optoelectronics) of graphene-based nanostructures. This work was supported by National Science Foundation Grant No. DMR07-05941, the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. Computational resources have been provided by Datastar at the San Diego Supercomputer Center.

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Authors

  • Li Yang

    • Department of Physics, University of California at Berkeley and Materials Sciences Division of Lawrence Berkeley National Laboratory

  • Marvin Cohen

    • Department of Physics, University of California at Berkeley and Materials Sciences Division of Lawrence Berkeley National Laboratory

  • Steven G. Louie

    • Department of Physics, UC Berkeley
    • Department of Physics, University of California at Berkeley and Materials Sciences Division of Lawrence Berkeley National Laboratory
    • UC Berkeley, and LBL
    • UC Berkeley
    • Dept. of Physics, UC Berkeley; MSD, LBNL
    • Department of Physics, University of California at Berkeley and Materials Sciences Division, Lawrence Berkeley National Laboratory
    • Molecular Foundry, LBNL and Physics Dept, UC Berkeley
    • UC Berkeley and LBNL
    • University of California at Berkeley and Lawrence Berkeley National Laboratory