Superconductivity in the new Platinum Germanides APt$_4$Ge$_{12}$ (A=Sr,Ba,La,Pr)

ORAL

Abstract

New germanium-platinum compounds with the filled-skutterudite crystal structure were synthesized. Magnetic susceptibility, specific heat, and electrical resistivity measurements find superconductivity in LaPt$_4$Ge$_{12}$ and PrPt$_4$Ge$_{12}$ below ca.\ 8\,K. The parameters of the normal and superconducting states were established. Strong electron-phonon coupling and a crystal electric field singlet groundstate is found for the Pr compound. Electronic structure calculations show a large density of states at the Fermi level, predominantly due to Ge $4p$ orbitals. Similar behavior, albeit with lower $T_c$, was observed for SrPt$_4$Ge$_{12}$ and BaPt$_4$Ge$_{12}$.

Authors

  • Helge Rosner

    • Max-Planck-Institute for Chemical Physics of Solids Dresden, Germany
  • Roman Gumeniuk

    • Max-Planck-Institute for Chemical Physics of Solids Dresden, Germany
  • Walter Schnelle

    • Max-Planck-Institute for Chemical Physics of Solids Dresden, Germany
  • Michael Nicklas

    • Max-Planck-Institute for Chemical Physics of Solids Dresden, Germany
  • Andreas Leithe-Jasper

    • Max-Planck-Institute for Chemical Physics of Solids Dresden, Germany
  • Yuri Grin

    • Max-Planck-Institute for Chemical Physics of Solids Dresden, Germany