Color properties, hydrogen bonding and magnetic interactions in (TBA)$_{3}$[Ni(NCS)$_{5}$]
ORAL
Abstract
We investigated the optical and vibrational properties of (TBA)$_{3}$[Ni(NCS)$_{5}$] a pentacoordinate Ni compound, and compared the results with the more traditional hexacoordinate analog (TEA)$_{4}$[Ni(NCS)$_{6}$]. Based upon electronic structure calculations, color properties of this high spin complex can be understood in terms of the crystal field splitting of the d-orbitals and their strong hybridization with the ligands. Temperature dependent vibrational studies show an additional splitting and softening of some of the modes at low temperature, which indicates enhanced hydrogen bonding between sulfur centers and organic ligands at low temperature as well as weak structural phase transitions.
*This work is supported by the National Science Foundation.
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