X-ray absorption spectroscopy of graphite oxides

ORAL

Abstract

We have investigated electronic structures of graphite oxide using x-ray absorption spectroscopy at carbon and oxygen K-edges. Unoccupied states such as $\pi ^{\ast }$ and $\sigma ^{\ast }$ states originating from sp$^{2}$ hybridization in graphite are also visible in the graphite oxide, even though the graphite oxide experiences a severe oxidation. Additional electronic states of the graphite oxide compared to that of pure graphite are ascribed to the functional groups such as epoxide, carboxyl, and hydroxyl groups that are present in the graphite oxide.

Authors

  • Hae-Kyung Jeong

    • BK21 Physics Division, Center for Nanotubes and Nanostructured Composites, Sungkyunkwan University
  • Leyla Colakerol

    • Department of Physics, Boston University, Boston, MA 02215, USA
  • Han-Jin Noh

    • Department of Physics, Chonnam National University, Gwangju 500-757, Korea
  • Yun Pyo Lee

    • BK21 Physics Division, Center for Nanotubes and Nanostructured Composites, Sungkyunkwan University
  • Mei Hua Jin

    • BK21 Physics Division, Center for Nanotubes and Nanostructured Composites, Sungkyunkwan University
  • Per-Anders Glans

    • Department of Physics, Boston University, Boston, MA 02215, USA
  • Jae-Young Kim

    • Pohang Accelerator Laboratory \& Department of Physics, POSTECH
  • Kevin E. Smith

    • Department of Physics, Boston University, Boston, MA 02215, USA
  • Chong Yun Park

    • BK21 Physics Division, Center for Nanotubes and Nanostructured Composites, Sungkyunkwan University
  • Young Hee Lee

    • Sungkyunkwan University
    • BK21 Physics Division, Center for Nanotubes and Nanostructured Composites, Sungkyunkwan University