Phase separation and inhomogeneity in La$_{1-x}$Sr$_{x}$CoO$_{3}$ single crystals

ORAL

Abstract

Nanoscale inhomogeneity in La$_{1-x}$ Sr$_{x}$CoO$_{3}$ has been studied in single crystal samples for 0.05$\le $ x $\le $0.3 using $^{139}$La NMR as a probe of the internal magnetic field distribution. The results show that phase separation occurs for x near the metal-insulator critical concentration x$_{C }$=0.17. The phase separation is confined to a much smaller range of x than that previously found in polycrystalline samples even though the bulk magnetic properties are similar. In single crystals with increasing x large, spin polarized (FM) regions merge into networks while smaller regions, identified as spin polarons, coexist with the larger regions. Insight into phase separation has been obtained by simulating the spectra with statistical model A phase diagram summarizing the evolution of the inhomogeneous internal field distribution with x and T will be presented.

Authors

  • William Moulton

    • National High Magnetic Field Laboratory 32310
    • National High Magnetic Field Lab
  • Robert Smith

    • National High Magnetic Field Laboratory 32310
    • National High Magnetic Field Lab
  • Michael Hoch

    • National High Magnetic Field Laboratory 32310
    • National High Magnetic Field Lab
  • Phillip Kuhns

    • National High Magnetic Field Laboratory
    • National High Magnetic Field Laboratory 32310
    • Department of Physics and National High Magnetic Field Laboratory, Florida State University
    • National High Magnetic Field Lab
  • Arneil Reyes

    • National High Magnetic Field Laboratory
    • National High Magnetic Field Laboratory 32310
    • Department of Physics and National High Magnetic Field Laboratory, Florida State University
    • National High Magnetic Field Lab
  • Greg Boebinger

    • National High Magnetic Field Laboratory 32310
    • National High Magnetic Field Lab
    • National High Magnetic Field Laboratory and Florida State University
    • MagLab/FSU
  • John Mitchell

    • Materials Science Division, Argonne National Laboratory, 9700 S. Cass Ave, Argonne IL 60439
    • Mat. Sci. Div., ANL
    • Argonne National Laboratory
    • Materials Science Division, Argonne National Laboratory
    • LANL
    • Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA
    • Argonne Natl Lab
    • Materials Science Division, Argonne National Laboratory, Argonne, IL
    • Argonne National Lab
  • C. Leighton

    • Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
    • University of Minnesota