Microscale Curveballs: Translational and Rotational Coupling of Colloids

ORAL

Abstract

Optically anisotropic MOON particles (modulated optical nanoparticles) allow the simultaneous measurement of translation and rotation for individual particles. Through chemical modification, these particles can be made hydrophilic, amphiphilic, or hydrophobic. Among those three, the boundary condition exhibits varying amounts of slip, which registers in the value of the rotational diffusion constant. Additionally, for the amphiphilic case, the translational and rotational motions are no longer independent of each other, exhibiting coupling due to the asymmetric hydrodynamic drag. Understanding these processes is fundamental to particle dynamics, with implications to kinetically limited processes such as the self-assembly of multi-unit proteins. Addressing the influence of these varied boundary conditions, this study presents single-particle tracking of micron-sized spherical colloids suspended in deionized water, tracked and quantified using home-written algorithms.

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Authors

  • Stephen Anthony

    • Department of Chemistry, University of Illinois
    • Dept of Chemistry, Univ of Illinois at Urbana-Champaign
    • Dept. of Chemistry, University of Illinois at Urbana and Champaign

  • Minsu Kim

    • Department of Physics, University of Illinois
    • Dept. of Physics, University of Illinois at Urbana and Champaign

  • Steve Granick

    • Department of Materials Science and Engineering, University of Illinois
    • University of Illinois at Urbana-Champaign