Phonons and the metal-insulator transition in VO$_2$

ORAL

Abstract

VO$_2$ undergoes a metal-insulator transition (MIT) at $T_C = 340 $~K, which is accompanied by a structural phase transition from a high temperature rutile phase to a low temperature monoclinic phase. Although VO$_2$ has been studied extensively for over 40 years, a clear understanding of the origin of the phase transition has not been forthcoming. Still at issue is the relative importance of electron-lattice and electron-electron interactions as driving mechanisms for the MIT. Here, we report the phonon dispersion of VO$_2$, measured along the rutile $\Gamma$-R direction using high resolution inelastic X-ray scattering. Unusual phonon behavior at the R point, as the MIT is approached, suggests significant electron-phonon coupling.

Authors

  • Sung Chang

  • Y. Janssen

  • P. C. Canfield

  • J. W. Kim

  • B. Sieve

  • A. I. Goldman

  • R. J. McQueeney

    • Ames Laboratory and Department of Physics, Iowa State University
  • A. Alatas

  • H. Sinn

    • Advanced Photon Source, Argonne National Laboratory