Plasma induced conversion of CO<sub>2 </sub>with water to useful compounds

ORAL

Abstract

Global energy consumption will increase 28% between 2015 and 2040, according to a report by the U.S. Department of Energy’s Energy Information Administration (EIA). The increased energy use will be matched by a 16% increase in energy-related carbon dioxide (CO2) emissions over that same period, with annual emissions rising from 33.9 billion metric tons in 2015 to 39.3 billion metric tons in 2040, according to EIA’s report. The CO2 conversion to produce sustainable carbonaceous fuels is the most promising option to tackle greenhouse gases in the short to medium term. CO2 is a promising renewable, cheap, and abundant C1 feedstock for producing valuable chemicals, such as CO.

Nonthermal plasma is a better option, as it can convert CO2 at near-ambient temperature and pressure [1-3]. The reduction of CO2 with H2O was carried out using the Arc plasma and possible production of organic compounds in the liquid phase and formation CO in the gas phase. The measured net conversion of CO2 to CO was close to 4% under optimal conditions. Although we also performed the 2D simulation using COMSOL Multiphysics® software to determine how the potential reaction generated gas phase was diffuse to the liquid phase.



*This work is supported by JSPS-KAKENHI grant number 22H01212. Additionally, partly supported by JSPS KAKENHI Grant Number JP16H03895, JP19H05462, JP19K14700, JP20H01893, JP20K14454, JSPS Core-to-Core Program "Data Driven Plasma Science", Plasma Bio Consortium, Adaptable and Seamless Technology transfer Program through Target-driven R&D (A-STEP) from Japan Science and Technology Agency (JST) Grant Number JPMJTR20RU, and Center for Low-temperature Plasma Sciences, Nagoya University.

Publication:
1. T. Ihara, M. Kiboku and Y. Iriyama, Bull. Chem. Soc. Jpn., 1994, 67, 312-314
2. X. Yao, Y. Zhang, Z. Wei, M. Chen, and W. Shangguan, Ind. Eng. Chem. Res. 2020, 59, 19133−19144
3. R. Snoeckx and A. Bogaerts, Chem. Soc. Rev., 2017, 46, 5805

Presenters

  • Pankaj Attri

    • Kyushu University

Authors

  • Pankaj Attri

    • Kyushu University
  • Takamasa Okumura

    • Kyushu University
    • Kyushu University, Japan
  • Kazunori Koga

    • Kyushu Univ
    • Kyushu University
    • Kyushu University, Japan
  • Kunihiro Kamataki

    • Kyushu Univ
    • Kyushu University
    • Kyushu University, Japan
  • Naho Itagaki

    • Kyushu University
    • Kyushu University, Japan
  • Masaharu Shiratani

    • Kyushu University
    • Kyushu University, Japan
  • Nozomi Takeuchi

    • Electrical and Electronic Engineering , Tokyo Institute of Technology
    • Department of Electrical and Electronic Engineering, Tokyo Institute of Technology
    • Tokyo Institute of Technology, Tokyo
    • Tokyo Institute of Technology