Vibrationally-resolved electron-impact excitation of molecular hydrogen
ORAL
Abstract
Molecular hydrogen and its isotopologues are present in a range of vibrationally excited states in fusion, atmospheric, and interstellar plasmas. Electron-impact excitation cross sections resolved in both final and initial vibrational levels of the target are required for modeling the properties of many low-temperature plasmas. Measurements of excitations in H$_2$ are typically limited to scattering on the ground vibrational state, and hence there is significant demand for accurate theoretical calculations of scattering on excited states. At low to intermediate energies, the currently recommended data are up to a factor of two higher than the available measurements for scattering on the ground vibrational state. Recent calculations performed using the convergent close-coupling (CCC) method have demonstrated the convergence of excitation cross sections with respect to the number of coupled channels, and yielded good agreement with experiment for scattering on the ground vibrational level of H$_2$. Here we extend the CCC method to provide a fully vibrationally-resolved description of e-H$_2$ scattering, providing results for excitation of all vibrational levels in several low lying singlet and triplet states, from all vibrational levels of the ground state.
*This work was supported by Curtin University, the Pawsey Supercomputing Centre, Los Alamos National Laboratory, the US Air Force Office of Scientific Research, the Australian Government Research Training Program, and the Forrest Research Foundation.
–