Neutral dissociation and strong-field ionization of iodine-containing halomethanes studied by time-resolved coincident ion momentum imaging
POSTER
Abstract
We study the UV-induced dissociation and NIR-strong-field ionization of CH3I and iodine-containing dihalomethanes using a time-resolved coincident ion momentum imaging technique. Upon absorption of a single 263 nm photon, the molecules dissociate primarily via C-I bond cleavage, and the dissociating neutral molecule is then ionized after a variable time delay by an intense 23-fs 790 nm pulse. We compare the observed delay-dependent ion kinetic energy release to a numerical model that relates the experimental data to the shape of the dissociative neutral and di-/tri-cationic potential energy curves. Our time-resolved coincidence data also allows identifying competing two- and three-photon excitation channels in the pump step.
*Supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Science, Chemical Science, Geosciences, and Bio-Science division, under grant no. DE-FG02-86ER13491.