Calculations of long-range three-body interactions for Li($2\,^{2}S$)-Li($2\,^{2}P$)-Li$^+$($1\,^{1}S$)

POSTER

Abstract

We theoretically investigate long-range interactions for a three-body system involving a ground state Li atom, an excited P state Li atom and a ground state Li ion, denoted by Li($2\,^{2}S$)-Li($2\,^{2}P$)-Li$^+$($1\,^{1}S$), with highly accurate variationally-generated nonrelativistic wave functions in Hylleraas coordinates. Using degenerate perturbation theory for the energies up to second-order, we evaluate the coefficients $C_3$ of the first-order induced and dipolar interactions, the coefficients $C_4$, $C_6$ and $C_8$ of the second-order additive interactions and the coefficients $C_5$ and $C_7$ of the second-order nonadditive interactions. Specific values of these coefficients will be given for different configurations of the three nuclei. The calculations are given for three like-nuclei for the cases of hypothetical infinite mass Li nuclei, and of real finite mass $^6{}$Li or $^7{}$Li nuclei. The results may be useful in the study of ultra-cold plasma.

*Work supported in part by NSERC, CAS/SAFEA, NBRPC, NNSF, and NSF

Authors

  • Pei-Gen Yan

    • U. New Brunswick
  • Li-Yan Tang

    • State Key Lab. Magnetic Resonance and Atomic and Molecular Physics, WIPM, CAS, Wuhan
    • State Key Lab. Magnetic Resonance, Atomic and Molecular Phys.
    • WIPM
  • Zong-Chao Yan

    • U. New Brunswick, Fredericton
    • U. New Brunswick & WIPM
  • James F Babb

    • ITAMP, Harvard-Smithsonian
    • ITAMP, Harvard-Smithsonian CfA
    • Harvard-Smithsonian CfA