Towards quantum-state-resolved ultracold chemical reactions of KRb molecules

ORAL

Abstract

Ultracold atoms and molecules provide a new platform to explore chemical reactions at ultralow temperatures. In this regime, reactions that are unlikely to happen classically could proceed surprisingly efficiently due to their quantum mechanical nature. We are investigating a likely~4-center reaction, 2KRb-\textgreater K2$+$Rb2$+$KE(1.24 meV), in the temperature regime below 1 micro-Kelvin. Towards this goal, we have built an apparatus that combines AMO techniques for ultracold reagent preparation and physical chemistry techniques for reaction product detection through resonance enhanced multiphoton ionization (REMPI) and velocity-map imaging (VMI). The micro-eV sensitivity of our VMI also provides a new tool to study ultracold Rydberg chemical reactions and few-body collisions.

*This work is supported by NSF, Arnold and Mabel Beckman Foundation, Alfred P. Sloan Foundation, AFOSR YIP

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Authors

  • Ming-Guang Hu

    • Harvard-MIT Center for Ultracold Atoms (CUA), Department of Chemistry and Chemical Biology, Harvard University

  • Yu Liu

    • Harvard-MIT Center for Ultracold Atoms (CUA), Department of Physics, Harvard University

  • Andrei Gheorghe

    • Harvard-MIT Center for Ultracold Atoms (CUA), Department of Physics, Harvard University

  • Yen-Wei Lin

    • Harvard-MIT Center for Ultracold Atoms (CUA), Department of Chemistry and Chemical Biology, Harvard University

  • David Grimes

    • Harvard-MIT Center for Ultracold Atoms (CUA), Department of Chemistry and Chemical Biology, Harvard University

  • Kang-Kuen Ni

    • Harvard-MIT Center for Ultracold Atoms (CUA), Department of Chemistry and Chemical Biology, Harvard University