Nonadiabatic dynamics in strong field molecular ionization with few cycle laser pulses

ORAL

Abstract

We study strong field ionization in several small molecules using few (4-10) cycle laser pulses. Using a supercontinuum light source, we are able to tune the laser wavelength (photon energy) over $\sim$200 nm (500 meV). We measure the photoelectron spectrum as a function of laser intensity, frequency, and bandwidth and demonstrate some control over the final state of the molecule in the ionization process. We find that intermediate multiphoton resonances and coupled electron nuclear dynamics result in ionization to different ionic continua. Interestingly, not only do these resonances strongly influence the final states produced in the cation, they can also dominate the PES whether the bandwidth is broad or narrow.

*This work has been supported by the National Science Foundation under grant number 1505679.

Authors

  • Vincent Tagliamonti

    • Department of Physics and Astronomy, Stony Brook University, Stony Brook NY 11794-3800
    • Stony Brook University, Stony Brook, NY
    • Stony Brook University
  • P\'eter S\'andor

    • Stony Brook University, Stony Brook, NY
  • Arthur Zhao

    • Stony Brook University, Stony Brook, NY
  • Tam\'as Rozgonyi

    • Institute of Materials and Environmental Chemistry of the H.A.S, Budapest
  • Philipp Marquetand

    • University of Vienna, Institute of Theoretical Chemistry, Wien, Austria
  • Thomas Weinacht

    • Stony Brook Unversity
    • State Univ of NY- Stony Brook
    • Department of Physics and Astronomy, Stony Brook University, Stony Brook NY 11794-3800
    • Stony Brook University, Stony Brook, NY