Progress towards using Feshbach Resonance Optimized Photoassociation spectroscopy to map excited electronic states of Rb dimers

POSTER

Abstract

We present progress towards measuring the complete vibrational spectrum of singly-excited molecular electronic potential curves of Rubidium using Feshbach optimized photoassociation. In this process, Feshbach resonances are used to enhance the photoassociation signal by altering the initial scattering wave function, increasing the overlap with the final excited-state bound wave function. We focus on the purely triplet $0^-_g$ state of Rb$_2$ that connects asymptotically to the $5^2S_{1/2} + 5^2P_{1/2}$ separated-atoms limit, due to its simple electronic structure. We present calculated absolute PA rates into vibrational states of excited electronic states that are inaccessible with conventional PA spectroscopy. These rates are found from a close-coupled scattering calculation.

Authors

  • Sean Krzyzewski

    • University of Oklahoma
  • Thomas Akin

    • University of Oklahoma
  • James Dizikes

    • University of Oklahoma
  • Gregory Parker

    • University of Oklahoma
  • Michael Morrison

    • University of Oklahoma
  • Eric Abraham

    • University of Oklahoma