Direct Measurement of the Zak phase in Topological Bloch Bands

Geometric phases that characterize the topological properties of Bloch bands play a fundamental role in the modern band theory of solids. We report on the direct measurement of the geometric phase acquired by cold atoms moving in one-dimensional optical lattices. Using a combination of Bloch oscillations and Ramsey interferometry, we extract the Zak phase---the Berry phase acquired during an adiabatic motion of a particle across the Brillouin zone---which can be viewed as an invariant characterizing the topological properties of the band. For a dimerized optical lattice, which models polyacetylene, we measure a difference of the Zak phase equal to 0.97(2)$\pi$ for the two possible polyacetylene phases with different dimerization. This indicates that the two dimerized phases belong to different topological classes, such that for a filled band, domain walls have fractional quantum numbers. Our work establishes a new general approach for probing the topological structure of Bloch bands in optical lattices.