External electric field alignment and long range forces between molecules

ORAL

Abstract

Long range electrostatic, induction and dispersion coefficients including terms of order $R^{-8}$ have been calculated by the sum over states method using time dependent density functional theory. The laboratory-frame transformation of electrostatic moments and van der Waals coefficients corresponding to the alignment of arbitrary molecules has been derived. From this transformation the effect of subsequent perturbations due to external electric fields have been computed for a sequence of molecules of experimental importance. Possible enhancements to the molecular alignment process due to choices in field geometries and strengths are investigated. Also derived are analytic solutions to the dressed-state laboratory-frame electrostatic moments and long range intermolecular potentials in the DC low-field limit.

*Department of Defense Air Force Office of Scientific Research MURI

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Authors

  • Jason Byrd

    • Department of Physics, University of Connecticut, Storrs, Connecticut 06269, USA
    • University of Connecticut Department of Physics

  • John Montgomery

    • University of Connecticut Department of Physics

  • Robin Cote

    • Department of Physics, University of Connecticut, Storrs, Connecticut 06269, USA
    • University of Connecticut
    • Dept. of Physics, University of Connecticut, Storrs, CT 06269
    • University of Connecticut Department of Physics