Enhanced Single-Photon Multi-Detachment in Anions of C$_{60}$ and Observation of a Scaling Law

POSTER

Abstract

Absolute single-photon multi-detachment cross sections in C$_{60}^-$ have been measured. We observe a large enhancement (2 and 2.5 times for double and triple detachment, respectfully) of the oscillator strength in the anion compared to neutral C$_{60}$. Although the anion spectra is qualitatively similar to that of multi-photoionzation in C$_{60}$, the anion spectra are substantially compressed in photon energy. The effect of the additional screening provided by the excess electron in the anion on the knock-off process is proposed in order to explain the observed energy scaling. We can also deduce from the results that plasmon resonances do not couple strongly into two- and three-electron removal channels in either the anion or the neutral systems, a surprising result given the intrinsic multi-electron character of the plasmon resonances.

*This work is funded by DOE, Office of Science, BES, Chemical Sciences, Geosciences and Biosciences Divisions. NDG and CWW acknowledge support from NSF, Grant No. 0757976. AM and SS acknowledge support from Deutsche Forschungsgemeinschaft.

Authors

  • R.C. Bilodeau

    • Western Michigan U., Kalamazoo MI
  • M. Hoener

    • Western Michigan U., Kalamazoo MI
  • N. Berrah

    • Western Michigan U., Kalamazoo MI
  • S. Schippers

    • Justus-Liebig-Universit\"{a}t, Giessen
  • A. M\"{u}ller

    • Justus-Liebig-Universit\"{a}t, Giessen
  • D.A. Esteves

    • U. of Nevada, Reno NV
  • R.A. Phaneuf

    • U. of Nevada, Reno NV
  • N.D. Gibson

    • Denison U., Granville OH
  • C.W. Walter

    • Denison U., Granville OH
  • A. Aguilar

    • LBNL-ALS, Berkeley CA
  • J.M. Rost

    • Max-Planck-Institut, Dresden