Photoabsorption spectrum of the Xe@C$_{60}$ endohedral fullerene

POSTER

Abstract

Photoabsorption spectrum of the Xe@C$_{60}$ endohedral fullerene has been studied using the time-dependent-density-functional-theory (TDDFT), which represents the dynamical polarizability of an interacting electron system by an off-diagonal matrix element of the resolvent of the Liouvilliam superoperator and solves the problem with the Lanczos algorithm. The method has been tested with the photoabsorption cross sections of the free Xe atom and C$_{60}$ fullerene. The result for the Xe@C$_{60}$ confirms the three main peaks observed in the recent measurement in the energy region of the Xe 4$d$ giant resonance [1] and shows the possibility that the Auger decay of the Xe$^+$ has been greatly suppressed if the ion is encapuslated inside C$_{60}$. It is suggested to perform the same measurement around 22 eV to check this possibility. \\[4pt] [1] A L D Kilcoyne et al, Phys. Rev. Lett. 105 213001 (2010).

*Supported by DOE, AFOSR and Army Research

Authors

  • Zhifan Chen

    • Clark Atlanta University
  • Alfred Z. Msezane

    • Clark Atlanta University