Multichannel Quantum Defect Theory for State-Resolved Molecular Collisions

ORAL

Abstract

With the advent of state-resolved, ultracold samples of ground state molecules, novel opportunities arise to explore the physics of cold and ultracold molecular collisions. We revisit state- resolved molecular scattering by employing a Multichannel Quantum Defect Theory treatment that allows us to describe long-range interactions by means of a few quantum defect parameters while the short-range physics can be modeled energy-independently. Being valid over a wide range of collision energies, the theory enables us to assess the effect of magnetic and electric fields on scattering resonances without the necessity of large-scale computations. Furthermore, a careful mapping of the resonances in cold collision experiments has the potential to provide insights on the physics of the short-range collision complex and its influence on the threshold scattering behavior.

Authors

  • Michael Mayle

    • JILA, University of Colorado and National Institute of Standards and Technology
  • Brandon P. Ruzic

    • JILA, University of Colorado and National Institute of Standards and Technology
  • John L. Bohn

    • JILA, University of Colorado and National Institute of Standards and Technology