Radiative association of H$_2$ and H$^-$ at low temperature: can we observe H$_3^-$ in the interstellar medium?

ORAL

Abstract

We develop the theory of radiative association of an atom and a diatomic molecule within a close-coupling framework. We apply it to the formation of H$_3^-$ after the low energy collision (below 0.5~eV) of H$_2$ with H$^-$. Using recently obtained potential energy and permanent dipole moment surfaces of H$_3^-$, we calculate the lowest rovibrational levels of the H$_3^-$ electronic ground state, and the cross section for the formation of H$_3^-$ by radiative association between H$^-$ and ortho- and para-H$_2$. We discuss the possibility for the H$_3^-$ ion to be formed and observed in the cold and dense interstellar medium in an environment with a high ionization rate and thus suggest a way to detect the H$_3^-$ ion in the interstellar medium. Such an observation would be a probe for the presence of H$^-$ in the interstellar medium.

*Work supported by tTriangle de la Physique (QCCM project) and NSF (grant PHY-0855622)

Authors

  • Mehdi Ayouz

    • Dep. of Chemistry, Marquette University
    • Department of Chemistry, Marquette University, Milwaukee 53201, USA
  • Olivier Dulieu

    • Laboratoire Aime Cotton, CNRS, Orsay
  • Maurice Raoult

    • Laboratoire Aime Cotton, CNRS, Orsay, France
  • Viatcheslav Kokoouline

    • University of Central Florida
    • Department of Physics, University of Central Florida, Orlando, Florida 32816, USA