Effect of Removing Occupied Orbitals Under the Single-Active-Electron Approximation
ORAL
Abstract
We present the results of using the single-active-electron approximation to treat multi-electron atoms in intense laser fields. In particular, we investigate the effect of not removing the occupied orbitals on the above threshold ionization spectrum, as well as the effect of how the occupied orbitals are removed. The occupied orbitals are eliminated from the system by various methods such as: a soft repulsive core [1], $\ell$-dependent pseudopotentials [2,3], and exactly in a basis set expansion. Special attention is paid to the high energy ($>$27 eV) portion of the spectrum where back-scattering occurs and the details of the atomic core are more strongly probed. \\[4pt] [1]H.G. Muller, Phys. Rev. A {\bf 60} 1341 (1999).\\[0pt] [2]M.B. Gaarde {\it et al.}, Phys. Rev. Lett. {\bf 84} 2822 (2000).\\[0pt] [3]W.J. Stevens {\it et al.}, Can. J. Chem. {\bf 70} 612 (1992).
*Supported by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy.