Bound states, resonances, and formation of the H$_3^-$ anion

POSTER

Abstract

Accurate potential energy surface and permanent dipole moments of the H$_3^-$ molecule are calculated. The obtained potential energy surface is used to obtain bound states, rotational constants, predissociated vibrational resonances and their lifetimes of the four isotopologues, H$_3^-$, H$_2$D$^-$, D$_2$H$^-$, and D$_3^-$, of the ion. We have also calculated the cross-section for the formation of H$_3^-$ by radiative association: H$_2+$H$^-\to$H$_3^- +\hbar\omega$. The obtained results suggest that the H$_3^-$ ions can be formed in the interstellar medium (ISM). An eventual detection of H$_3^-$ in the ISM would also be a proof that the H$^-$ ion is present in the ISM.

*Supported by Triangle de la Physique contract QCCM and the National Science Foundation grant PHY-0855622

Authors

  • Viatcheslav Kokoouline

    • Department of Physics, U Central Florida
  • Mehdi Ayouz

    • Laboratoire Aime Cotton, U Paris-XI, CNRS, Orsay
    • Laboratoire Aim\'e Cotton, CNRS, Universit\'e de Paris Sud, Orsay, France
  • Jacques Robert

    • Laboratoire Aime Cotton, U Paris-XI, CNRS, Orsay
  • Olivier Dulieu

    • Laboratoire Aime Cotton, U Paris-XI, CNRS, Orsay
    • Laboratoire Aime Cotton, CNRS, Orsay, France