Electron Impact Excitation of Molecular Nitrogen: Excitation of the $C~^{3}\Pi_{u}$, $E~^{3}\Sigma_{g}^{+}$, and $a^{\prime\prime}~^{1}\Sigma_{g}^{+}$ States and Vibrationally-Resolved Excitation of the $C~^{3}\Pi_{u}~(\nu^{\prime})$ State

POSTER

Abstract

Differential cross sections (DCSs) were investigated for electron impact excitation of the $C~^{3}\Pi_{u}$, $E~^{3} \Sigma_{g}^{+}$, and $a^{\prime\prime}~^{1}\Sigma_{g}^{+}$ states from the ground state in N$_{2}$. The DCSs were obtained from new measurements of energy-loss spectra in the region of 10.75eV to 12.75eV measured at incident energies between 13eV and 100eV and for scattering angles ranging from $5^{\circ}$ to $130^{\circ}$. Vibrationally-resolved DCSs are presented for electron impact excitation from the ground state to the $C~^{3}\Pi_{u}~(\nu^{\prime})$ state, where $\nu^{\prime} $=0, 1, 2, 3, and 4. Relative excitation probabilities for the vibrational levels of the $C~^{3}\Pi_{u}$ state are shown to demonstrate non-Franck-Condon behavior for excitation energies less than approximately 50eV.

*This work was carried out at CSUF and JPL, Caltech, under contracts with NASA and NSF.

Authors

  • C.P. Malone

  • P.V. Johnson

  • J.A. Young

  • I. Kanik

    • Jet Propulsion Laboratory, Caltech, MS 183-601, 4800 Oak Grove Drive, Pasadena, CA 91109 USA
  • S. Rahman

    • UCLA
  • B. Ajdari

  • M.A. Khakoo

    • Physics Department, Cal State Fullerton, 800 N. State College, Fullerton, CA 92834 USA