Photoionization of atoms confined inside bucky-ball onions

ORAL

Abstract

We report on a theoretical study of photoionization of the atom $A$ placed at the center of nested fullerenes $C_{60}$, $C_{240}$, and $C_{540}$; the formation termed ``bucky-ball onion''. The fullerene cages are represented by spherical well potentials of adjusted inner radii, widths, and potential depths. The \textit{inner-shell} photoionization largely rules out the impact of both the change in the structure of the deepest inner-shell due to the confinement and polarizability of a bucky-ball on the photoionization process. In turn, the \textit{near-threshold} ionization eliminates the impact of the granular structure of the bucky-ball cage on the photoionization process. This makes our model workable, to a good approximation. Progressively complicating trends in the abundance of appearing confinement type resonances in the photoionization spectra with increasing number of nested bucky-balls is unraveled and the corresponding interpretation is given. The $1s$- and $2p$-near- threshold photoionization of $Ar$ from $Ar@C_{60}$, $Ar@C_{60}@C_{240}$, and $Ar@C_{60}@C_{240}@C_{540}$ is chosen as the case study.

*This work was supported by NSF Grants PHY-0652704 and PHY-024394, DoE, BES, as well as UNA Research and UNA CAS Grants.

Authors

  • Valeriy Dolmatov

    • University of North Alabama, Florence, AL
  • Patrick Brewer

    • University of North Alabama, Florence, AL
  • S.T. Manson

    • Department of Physics and Astronomy, Georgia State University, Atlanta, GA 30303
    • Georgia State University, Atlanta, GA 30303
    • Georgia State University, Atlanta, GA
    • Georgia State University