K-shell Fluorescence Yields of Li- to F-like Ions

We have investigated the accuracy of the commonly-used fluorescence/Auger database. These data were determined from configuration average, LS, singly-charged atomic physics calculations and were then scaled up through Z=30 for all isoelectronic sequences through the iron peak elements. We have carried out new calculations, using the AUTOSTRUCTURE package, and demonstrate the significance of including properly such physical effects as correct configuration averaging (CA), semi-relativistic (i.e., spin-orbit) effects, and the previously-overlooked need to tailor the CA itself to the specific physical process of interest, showing that the extant database includes significant inaccuracies. Finally, we have completed an investigation of the isoelectronic sequences of all second-row ions. This work was supported in part by NASA APRA and SHP SR\&T programs.