H$_2$ dissociation due to collision with He
POSTER
Abstract
Cross sections for dissociation of H$_2$ due to collision with He are calculated for excited rovibrational states using the quantum mechanical coupled states approximation. An $L^2$ Sturmian basis set with multiple length scales is used to to provide a discrete represention of the H$_2$ continuum which includes orbiting resonances and a non-resonant background. Cross sections are given over a range of translational energies for resonant and non-resonant dissociation together with the most important bound state transitions for four different initial states. The results demonstrate that it is possible to compute converged quantum mechanical cross sections using basis sets of modest size.
*supported by the NASA Spitzer Space Telescope Theoretical Research Program