Long-range interactions between two excited helium atoms

POSTER

Abstract

Using variational wave functions in correlated Hylleraas coordinates, we have precisely calculated the dispersion coefficients $C_n$ (with n up to 10) for the long-range interaction between two excited helium atoms including the effect of finite nuclear mass. In this work, the long-range interaction coefficients reported are $C_3$, $C_6$, $C_8$, $C_9$, and $C_{10}$ for He$(2\,^1\!S)$--He$(2\,^1\!P)$; $C_6$, $C_8$, and $C_{10}$ for He$(2\,^3\!S)$--He$(2\,^1\!P)$; and $C_5$, $C_6$, $C_8$, and $C_ {10}$ for He$(2\,^1\!P)$--He$(2\,^1\!P)$ and He$(2\,^1\!P)$--He$(2\,^3\!P) $ for the $\Delta$, $\Pi$, and $\Sigma$ molecular states.

*This work is supported in part by NSERCC and by NSF

Authors

  • J.-Y. Zhang

  • Z.-C. Yan

    • Department of Physics, University of New Brunswick, Fredericton, New Brunswick, Canada E3B 5A3
  • D. Vrinceanu

    • T-4 Group, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
  • J.F. Babb

  • H.R. Sadeghpour

    • ITAMP, Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138, USA