A semi-quantitative model for molecular dissociation in an intense laser pulse

ORAL

Abstract

We have developed a simple model that describes the intensity and angular dependence of molecular dissociation and predicts the kinetic energy of the fragments. Moreover, the model yields relatively simple analytic expressions for each of these dependencies that makes possible semi-quantitative estimates for the mechanisms of bond-softening and bond-hardening. The predictions of the model are in general agreement with our measurements for net one, two, and three photon dissociation of H$_2^+$ in a 45~fs pulse.

*Supported by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy

Authors

  • B.D. Esry

    • J.R. Macdonald Laboratory, Department of Physics, Kansas State University
    • Physics Department, Kansas State University
    • J. R. Macdonald Laboratory, Department of Physics, Kansas State University, Manhattan, KS 66506
  • I. Ben-Itzhak

  • P.Q. Wang

  • A.M. Sayler

  • K.D. Carnes

    • J.R. Macdonald Laboratory and Department of Physics, Kansas State University