Abrupt structural transition in V 2 O 3 revealed by pair distribution function analysis

ORAL

Abstract

V$_{\mathrm{2}}$O$_{\mathrm{3}}$ is a popular system for studying Mott insulators, which are materials that are driven into an insulating state by strong electron correlations. Despite decades of research, a complete understanding of the metal-insulator transition in V$_{\mathrm{2}}$O$_{\mathrm{3}}$ has not been conclusively established. Here, we present comprehensive atomic and magnetic pair distribution function (PDF) analyses of V$_{\mathrm{2}}$O$_{\mathrm{3}}$ using both x-ray and neutron total scattering measurements, shedding new light on the mechanism of the transition from the point of view of short-range structural and magnetic correlations on both sides of the transition. We observe an abrupt structural transition with no hint of short-range monoclinic distortions above the transition temperature. This lack of structural fluctuations above the transition contrasts with the known presence of magnetic fluctuations in the high-temperature state, suggesting that the lattice degree of freedom plays a secondary role behind the spin degree of freedom in the transition mechanism.

Authors

  • Ethan Fletcher

    • Brigham Young University-Provo
  • Benjamin Frandsen

    • Brigham Young University-Provo
    • BYU
    • Brigham Young University
  • Kentaro Higashi

    • Kyoto University
  • Hiroshi Kageyama

    • Kyoto University